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Say you shoot out two screenshot galleries every day, each containing 10 images That s 140 images every week, or 560 per month At around 700 KB each, that adds up for sure; to over 380 MB per month actually You don t need to be a mathematician to understand that such a site will require a lot of megabytes in bandwidth, as well as storage in the long run That s why photo-sharing sites are interesting Pumping images in to Flickr means that you needn t worry about those things Now, it may be a bit of a stretch to have the big videogame sites running their screenshot library on Flickr, but what about the ones relying on more traditional photography There is money to be saved here, by doing a YouTube with images as well.

It is interesting to study whether the azobenzene molecular conformational rearrangements can result in changes to bulk phenomena, or even to macroscopic motion. The rst consideration is whether the material expands to an appreciable extent. In monolayers, it is well established that the larger molecular size of the cis isomer leads to a corresponding lateral expansion (Higuchi et al., 1995b), which can modify other bulk properties. For instance, this allows photomodulation of a monolayer s water contact angle (Siewierski et al., 1996) or surface potential (Stiller et al., 1999). Using uorinated azo polymer, good photocontrol (Feng et al., 2001) and photopatterning (Moller et al., 1998) of wettability has been demonstrated. A monolayer of azo-modi ed calixarene, when irradiated with a light gradient, produced a gradient in surface energy suf cient to move a macroscopic oil droplet (Ichimura et al., 2000), suggesting possible applications in micro uidics. Modest photoinduced contact angle changes for thin polymer lms have also been reported (Sarkar et al., 2001). Recently an azobenzene copolymer assembled into polyelectrolyte multilayer showed a modest 21 change in contact angle with UV light irradiation. However, when the same copolymer was assembled onto a patterned substrate, the change in contact angle upon irradiation was enhanced to 701 (Jiang et al., 2005). It is well established that

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surface roughness plays a role in contact angle and many systems can be optimized to give rise to a large change in surface properties In layered inorganic systems with intercalated azobenzenes, reversible photochanges in the basal spacing (on the order of 4%) can be achieved (Fujita et al, 1998, 2001) In polymer lms, there is some evidence that the lm thickness increases, as measured by ellipsometry (Shi et al, 1991b) (the refractive index certainly changes [Ivanov et al, 1995], but this is not an unambiguous demonstration of expansion contraction) Experiments that show that external applied pressure tends to hinder photoisomerization (Kleideiter et al, 2000) are related Photocontraction for semicrystalline main-chain azos has been measured (Eisenbach, 1980b; Agolini and Gay, 1970) This photomechanical response presumably occurs because of the shortening of the polymer chains upon trans-cis conversion.

After all, even the best of them are embedding videos these days, so why not images Naturally there are drawbacks, most importantly the fact that if your image host goes out of business you ll lose all your images You can sort that out with backups, of course, but you d need to put them in again manually On the other hand, these services are rarely small players, and if you stick to the big ones it isn t likely they ll go away Again, if you can rely on YouTube you should be able to rely on the likes of Flickr There is some trust involved, after all Another issue is loading time If your image host is struggling to serve the images, for one reason or another, your site will suffer for it.

However, photoexpansion would seem to be contradicted by positron lifetime experiments that suggest no change in microscopic free volume cavity size during irradiation (Algers et al, 2004) More conclusive experiments are in order The most convincing demonstration of macroscopic motion due to azo isomerization is the mechanical bending and unbending of a free-standing polymer lm (Ikeda et al, 2003; Yu et al, 2003) The macroscopic bending direction may be selected either with polarized light or by aligning the chromophores with rubbing Bending occurs in these relatively thick lms because the free surface (which absorbs light) contracts, whereas the interior of the lm (which is not irradiated owing to the strong absorption of the upper part of the lm) does not contract Because the direction of bending can be controlled with polarized light, the materials enable full directional photomechanical control (Yu et al, 2005).

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